Researchers develop accelerated synthesis method for ultralong graphene nanoribbons
Researchers from POLYMAT at the University of the Basque Country UPV/EHU, Max Planck Institute for Polymer Research and the University of Aveiro have reported an accelerated iterative approach enabling the synthesis of a series of length-controlled, ultralong atomically precise graphene nanoribbons (GNRs). The longest GNR displays a 920-atoms core with a 35.8-nm long (147 linearly fused rings) backbone that has been obtained in just three synthetic steps from building blocks of ∼2 nm in length.
A Lego-like synthesis previously produced record-breaking nanoribbons of 30, then 53 fused rings. Now, a similar ‘accelerated’ modular methodology made a molecular nanoribbon that is triple the longest ever made – in just three simple steps. The resulting graphene nanoribbon is almost 36nm long, with its 147 linearly linked rings and a conjugated core of 920 atoms. The first experiments, although preliminary, envision applications in electronics and optoelectronics, thanks to fluorescence features that reportedly outperform state-of-the-art quantum dots.