A team of researchers led by Columbia University have developed a new method to finely tune adjacent layers of graphene, in a research that provides new insights into the physics underlying the material's intriguing characteristics.
"Our work demonstrates new ways to induce superconductivity in twisted bilayer graphene, in particular, achieved by applying pressure," said Cory Dean, assistant professor of physics at Columbia and the study's principal investigator. "It also provides critical first confirmation of last year's MIT results - that bilayer graphene can exhibit electronic properties when twisted at an angle - and furthers our understanding of the system, which is extremely important for this new field of research".
However, reaching that magic angle has proven difficult. "The layers must be twisted to within roughly a tenth of a degree around 1.1, which is experimentally challenging," Dean said. "We found that very small errors in alignment could give entirely different results."
So Dean and his colleagues, who included scientists from the National Institute for Materials Science and the University of California, Santa Barbara, set out to test whether magic-angle conditions could be achieved at bigger rotations.
"Rather than trying to precisely control the angle, we asked whether we could instead vary the spacing between the layers," said Matthew Yankowitz, a postdoctoral research scientist in Columbia's physics department and first author on the study. "In this way any twist angle could, in principle, be turned into a magic angle."
They studied a sample with twist angle of 1.3 degrees - only slightly larger than the magic angle but still far enough away to preclude superconductivity.
Applying pressure transformed the material from a metal into either an insulator or a superconductor - depending on the number of electrons in the material.
"Remarkably, by applying pressure of over 10,000 atmospheres we observe the emergence of the insulating and superconducting phases," Dean said. Additionally, the superconductivity develops at the highest temperature observed in graphene so far, just over 3 degrees above absolute zero."
To reach the high pressures needed to induce superconductivity, the team worked closely with the National High Magnetic Field user facility, known as the Maglab, in Tallahassee, Florida.
"This effort was a huge technical challenge," said Dean. "After fabricating one of most unique devices we've ever worked with, we then had to combine cryogenic temperatures, high magnetic fields, and high pressure - all while measuring electrical response. Putting this all together was a daunting task and our ability to make it work is really a tribute to the fantastic expertise at the Maglab."
The researchers believe it may be possible to enhance the critical temperature of the superconductivity further at even higher pressures. The ultimate goal is to one day develop a superconductor which can perform under room temperature conditions, and although this may prove challenging in graphene, it could serve as a roadmap for achieving this goal in other materials.
Andrea Young, assistant professor of physics at UC Santa Barbara, a collaborator on the study, said the work clearly demonstrates that squeezing the layers has same effect as twisting them and offers an alternative paradigm for manipulating the electronic properties in graphene.
"Our findings significantly relax the constraints that make it challenging to study the system and gives us new knobs to control it," Young said.
Dean and Young are now twisting and squeezing a variety of atomically-thin materials in the hopes of finding superconductivity emerging in other two-dimensional systems.