Graphene and metal nitrides create improved asymmetric supercapacitors

Researchers at A*STAR have developed an 'asymmetric' supercapacitor based on vertically aligned graphene nanosheets coated with iron nitride and titanium nitride as the anode and cathode, that could be a viable energy storage solution.

While traditional supercapacitors use the same material for both electrodes, the anode and cathode in an asymmetric supercapacitor are made up of different materials. Scientists initially used metal oxides as asymmetric supercapacitor electrodes, but as metal oxides do not have particularly high electrical conductivity and become unstable over long operating cycles, it was clear that a better alternative was needed.

A supercapacitor's viability is largely determined by the materials of which its anodes and cathodes are comprised. These electrodes must have a high surface area per unit weight, high electrical conductivity and capacitance and be physically robust so they do not degrade during operation in liquid or hostile environments.

Unlike traditional supercapacitors, which use the same material for both electrodes, the anode and cathode in an asymmetric supercapacitor are made up of different materials. Scientists initially used metal oxides as asymmetric supercapacitor electrodes, but, as metal oxides do not have particularly high electrical conductivities and become unstable over long operating cycles, it was clear that a better alternative was needed.

Metal nitrides such as titanium nitride offer both high conductivity and capacitance, and so they make for a promising alternative. The problem is that they tend to oxidize in watery environments, which limits their lifetime as an electrode. A solution to this is to combine them with more stable materials - which is what the researchers did by incorporating the metal nitride electrodes with stacked sheets of graphene.

To get the maximum benefit from the graphene surface, the team used a precise method for creating thin-films, a process known as atomic layer deposition, to grow two different materials on vertically aligned graphene nanosheets: titanium nitride for their supercapacitor's cathode and iron nitride for the anode. The cathode and anode were heated to 800 and 600 degrees Celsius respectively, and allowed to slowly cool. The two electrodes were then separated in the asymmetric supercapacitor by a solid-state electrolyte, which prevented the oxidization of the metal nitrides.

The researchers tested their supercapacitor devices and showed they could cycle 20,000 times and exhibit both high capacitance and high power density. They state that these improvements are due to the ultra-high surface area of the vertically aligned graphene substrate and the atomic layer deposition method that enables full use of it. In future research, the scientists want to enlarge the working-voltage of the device to increase energy density even further.

Source: phys.org